CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine.
نویسندگان
چکیده
Photocatalytic CO(2) reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 66 شماره
صفحات -
تاریخ انتشار 2012